Material Safety Data Sheet
    Trans,Trans-2,4-Hexadien-1-ol, 99%
ACC# 00082
  
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Section 1 - Chemical Product and Company Identification | 
  
MSDS Name: Trans,Trans-2,4-Hexadien-1-ol, 99%
Catalog Numbers:
     AC325570000, AC325570100, AC325570500
Synonyms:
     None Known.
Company Identification:
 
 
 
 
 
 
 
Acros Organics N.V.
 
 
 
 
 
 
 
One Reagent Lane
 
 
 
 
 
 
 
Fair Lawn, NJ  07410
For information in North America, call:   800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
  
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Section 2 - Composition, Information on Ingredients
 | 
  | CAS# | 
    Chemical Name | 
    Percent | 
    EINECS/ELINCS | 
|   17102-64-6 | 
Trans,Trans-2,4-Hexadien-1-ol | 
   99%    | 241-173-4 | 
  
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Section 3 - Hazards Identification
 | 
EMERGENCY OVERVIEW
Appearance: colorless liquid. Flash Point: 72 deg C.
 Warning! Causes eye, skin, and respiratory tract
irritation. Combustible liquid and vapor.
May cause central nervous system depression. Air sensitive.
Target Organs: Central nervous system.
Potential Health Effects
     
Eye:
          Causes eye irritation.  May cause chemical conjunctivitis and
          corneal damage.
     
Skin:
          Causes skin irritation. May cause cyanosis of the extremities.
     
Ingestion:
          May cause gastrointestinal irritation with nausea, vomiting and
          diarrhea. The toxicological properties of this substance have not
          been fully investigated.
     
Inhalation:
          Causes respiratory tract irritation. The toxicological properties of
          this substance have not been fully investigated. Aspiration may lead
          to pulmonary edema. Inhalation at high concentrations may cause CNS
          depression and asphixiation.
     
Chronic:
          Effects may be delayed.
  
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Section 4 - First Aid Measures
 | 
     
Eyes:
          Immediately flush eyes with plenty of water for at least 15 minutes,
          occasionally lifting the upper and lower eyelids. Get medical aid.
     
Skin:
          Get medical aid. Flush skin with plenty of water for at least 15
          minutes while removing contaminated clothing and shoes. Wash clothing
          before reuse.
     
Ingestion:
          Never give anything by mouth to an unconscious person. Get medical
          aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
          drink 2-4 cupfuls of milk or water. Wash mouth out with water.
     
Inhalation:
          Remove from exposure and move to fresh air immediately. If not
          breathing, give artificial respiration. If breathing is difficult,
          give oxygen. Get medical aid. Do NOT use mouth-to-mouth
          resuscitation.
     
Notes to Physician:
          Treat symptomatically and supportively.
  
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Section 5 - Fire Fighting Measures
 | 
     
General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear. During a fire, irritating and highly toxic gases
          may be generated by thermal decomposition or combustion. Use water
          spray to keep fire-exposed containers cool. Combustible liquid.
          Vapors may be heavier than air.  They can spread along the ground and
          collect in low or confined areas. Containers may explode when heated.
          Runoff from fire control or dilution water may cause pollution.
     
Extinguishing Media:
          In case of fire, use water, dry chemical, chemical foam, or
          alcohol-resistant foam. Use water spray to cool fire-exposed
          containers. Use water spray, dry chemical, carbon dioxide, or
          chemical foam. Use water spray, dry chemical, carbon dioxide, or
          appropriate foam.
Flash Point: 72 deg C ( 161.60 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
                  Upper: Not available.
     
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
  
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Section 6 - Accidental Release Measures
 | 
     
General Information: Use proper personal protective equipment as indicated
                          in Section 8.
     
Spills/Leaks:
          Absorb spill with inert material (e.g. vermiculite, sand or earth),
          then place in suitable container. Avoid runoff into storm sewers and
          ditches which lead to waterways. Clean up spills immediately,
          observing precautions in the Protective Equipment section. Remove all
          sources of ignition. Use a spark-proof tool. Provide ventilation.
          Place under an inert atmosphere.
  
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Section 7 - Handling and Storage
 | 
     
Handling:
          Wash thoroughly after handling. Use only in a well-ventilated area.
          Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
          skin, and clothing. Empty containers retain product residue, (liquid
          and/or vapor), and can be dangerous. Keep container tightly closed.
          Keep away from heat, sparks and flame. Avoid ingestion and
          inhalation. Handle under an inert atmosphere. Store protected from
          air. Wash clothing before reuse. Do not pressurize, cut, weld, braze,
          solder, drill, grind, or expose empty containers to heat, sparks or
          open flames.
     
Storage:
          Keep away from heat, sparks, and flame. Keep away from sources of
          ignition. Store in a tightly closed container. Store in a cool, dry,
          well-ventilated area away from incompatible substances. Do not expose
          to air. Store under an inert atmosphere.
  
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Section 8 - Exposure Controls, Personal Protection
 | 
     
Engineering Controls:
          Facilities storing or utilizing this material should be equipped
          with an eyewash facility and a safety shower. Use adequate
          ventilation to keep airborne concentrations low.
Exposure Limits
  | Chemical Name | 
    ACGIH | 
    NIOSH | 
    OSHA - Final PELs | 
| Trans,Trans-2,4-Hexadien-1-ol
 | 
none listed
 | 
none listed
 | 
none listed
 | 
     
OSHA Vacated PELs:
          Trans,Trans-2,4-Hexadien-1-ol:
             No OSHA Vacated PELs are listed for this chemical.
     
Personal Protective Equipment
                 
Eyes:
                       Wear appropriate protective eyeglasses or chemical
                       safety goggles as described by OSHA's eye and face
                       protection regulations in 29 CFR 1910.133 or European
                       Standard EN166.
                 
Skin:
                       Wear appropriate protective gloves to prevent skin
                       exposure.
             
Clothing:
                       Wear appropriate protective clothing to prevent skin
                       exposure.
          
Respirators:
                       Follow the OSHA respirator regulations found in 29
                       CFR 1910.134 or European Standard EN 149. Use a
                       NIOSH/MSHA or European Standard EN 149 approved
                       respirator if exposure limits are exceeded or if
                       irritation or other symptoms are experienced.
  
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Section 9 - Physical and Chemical Properties
 | 
Physical State:  Liquid
Appearance:      colorless
Odor:            Not available.
pH:              Not available.
Vapor Pressure:  Not available.
Vapor Density:   3.38
Evaporation Rate:Not available.
Viscosity:       Not available.
Boiling Point:   80 deg C @ 12.00mmHg
Freezing/Melting Point:30.5 - 31.5 deg C
Decomposition Temperature:Not available.
Solubility:      soluble in alcohol,ether and oils
Specific Gravity/Density:.8710g/cm3
Molecular Formula:CH3CH=CHCH=CHCH2OH
Molecular Weight:98.14
  
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Section 10 - Stability and Reactivity
 | 
     
Chemical Stability:
          Stable at room temperature in closed containers under normal storage
          and handling conditions. May discolor on exposure to air.
     
Conditions to Avoid:
          Incompatible materials, light, ignition sources, exposure to air,
          excess heat.
     
Incompatibilities with Other Materials:
          Oxidizing agents, acid anhydrides, acid chlorides, air.
     
Hazardous Decomposition Products:
          Carbon monoxide, irritating and toxic fumes and gases, carbon
          dioxide.
     
Hazardous Polymerization: Has not been reported
  
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Section 11 - Toxicological Information
 | 
     
RTECS#:
     
CAS# 17102-64-6
unlisted.
     
LD50/LC50:
          Not available.
     
Carcinogenicity:
       CAS#   17102-64-6:
          Not listed by ACGIH, IARC, NTP, or CA Prop 65.
     
Epidemiology:
No information found
     
Teratogenicity:
No information found
     
Reproductive Effects:
No information found
     
Mutagenicity:
No information found
     
Neurotoxicity:
No information found
     
Other Studies:
  
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Section 12 - Ecological Information
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          No information available.
  
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Section 13 - Disposal Considerations
 | 
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
  
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Section 14 - Transport Information
 | 
  |        | 
    US DOT | 
    Canada TDG | 
| Shipping Name: | 
Not regulated as a hazardous material | 
No information available. | 
| Hazard Class: | 
 | 
 | 
| UN Number: | 
 | 
 | 
| Packing Group: | 
 | 
 | 
  
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Section 15 - Regulatory Information
 | 
 US FEDERAL
     
TSCA
     CAS# 17102-64-6 is listed on the TSCA inventory.
        
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
        
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
        
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
        
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
        
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
        
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
        
Section 313
     No chemicals are reportable under Section 313.
     
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
     
Clean Water Act:
     None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
     None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
     
OSHA:
     None of the chemicals in this product
are considered highly hazardous by OSHA.
 
STATE
          CAS#   17102-64-6 is not present on
     state lists from CA, PA, MN, MA, FL, or NJ.
 
California Prop 65
     
California No Significant Risk Level:
     None of the chemicals in this product are listed.
 
European/International Regulations
     European Labeling in Accordance with EC Directives
          Hazard Symbols:
      XI
          
Risk Phrases:
     R 36/37/38  Irritating to eyes, respiratory system and skin.          
          
Safety Phrases:
     S 26  In case of contact with eyes, rinse immediately with plenty of  
     water and seek medical advice.                                        
     S 37/39  Wear suitable gloves and eye/face protection.                
   
WGK (Water Danger/Protection)
     CAS# 17102-64-6: No information available.
   Canada - DSL/NDSL
     CAS# 17102-64-6 is listed on Canada's NDSL List.
   Canada - WHMIS
     This product has a WHMIS classification of D2B, B3.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
   Canadian Ingredient Disclosure List
  
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Section 16 - Additional Information
 | 
     MSDS Creation Date: 11/09/1998  
Revision #5 Date:  3/04/2004
     The information above is believed to be accurate and represents the best
     information currently available to us. However, we make no warranty of
     merchantability or any other warranty, express or implied, with respect to
     such information, and we assume no liability resulting from its use. Users
     should make their own investigations to determine the suitability of the
     information for their particular purposes. In no event shall Fisher be liable
     for any claims, losses, or damages of any third party or for lost profits
     or any special, indirect, incidental, consequential or exemplary
     damages, howsoever arising, even if Fisher has been advised of
     the possibility of such damages.