FISHER SCIENTIFIC CO CHEMICAL DIV. -- BARIUM CARBONATE -- 6810-00-824-9072
===================== Product Identification ===================== Product ID:BARIUM CARBONATE MSDS Date:12/20/1994 FSC:6810 NIIN:00-824-9072 === Responsible Party === Company Name:FISHER SCIENTIFIC CO CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO Address:2000 PARK LN Box:City:PITTSBURGH State:PA ZIP:15275 Country:US Phone:412-490-8586 CAGE:22527 Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM CARBONATE CAS:513-77-9 RTECS #:CQ8600000 Fraction by Wt: 99% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG BA/M3 ACGIH TLV:2 MG BA/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 418 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:**IRRITANT-TOXIC** EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:TOXIC.MAY CAUSE GI TRACT IRRITATION.INHAL:250MG/M3 OF BARIUM IS IMMEDIATELY DANGEROUS TO LIFE AND HEALTH.MAY CAUSE RESPIRA TORY IRRITATION.CHRONIC:DERMATITIS,KIDNEY DAMAGE. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INGEST:NAUSEA,VOMITING,DIARRHEA(WITH OR WITHOUT COLIC AND SALIVATION),DRY MOUTH,SENSE OF ORAL CONSTRICTION,METALLIC TASTE,VISUAL DISTURBANCES,IMPAIRED HEART AND MUSCLE LEADING TO PARALYSIS,ANXIETY,WEA KNESS,HIGH BLOOD PRESSURE,CONVULSIONS.EYES/SKIN:REDNESS,PAIN.INHAL:COUGH,LABORED BREATHING. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING KIDNEY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP OR MILD DETERGENT AND WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH NORMAL SALINE OR WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR .MAINTAIN AIRWAY AND BLOOD PRESSURE.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:GET MEDICAL ATTENTION.IF CONSCIOUS,NDUCE VOMITING BY STICKING FINGER DOWN THROAT(SUPPLIMENTAL). ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY,DRY CHEMICAL,REGULAR FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.FIGHT FIRE FROM UPWIND.DO NOT SCATTER MATL WITH HIGH PRESSURE WATER STREAM. Unusual Fire/Explosion Hazard:MAY BURN BUT DOES NOT READILY IGNITE.CONTAINERS MAY BURST FROM HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILL.SOAK UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL.SHOVEL DRY SPILLS INTO A DRY CONTAINER. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:FOLLOW LABEL DIRECTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NIOSH/MSHA APPROVED RESPIRATOR FOR DUST AND MISTS,DEPENDING ON THE AIRBORN CONCENTRA TION. Ventilation:USE LOCAL EXHAUST OR PROCESS ENCLOSURE. Protective Gloves:CHEMICALLY RESISTANT GLOVES Eye Protection:SPLASH OR DUST-PROOF GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health BARIUM POISONING ANTIDOTE-30G SODIUM SULFATE IN 250ML WATER ORAL,REPEAT IN ONE HOUR.ADMINISTRATION OF BARIUM SALTS INTRAVENEOUSLY IS HAZARDOUS(BARIUM SALTS PRECIPITATE POSSIBLY CAUSING RENAL FAILURE). ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:2372F,1300C Melt/Freeze Pt:M.P/F.P Text:1492F,811C Decomp Temp:Decomp Text:2372F,1300C Vapor Pres:<0.1 Spec Gravity:4.43 Solubility in Water:NEGLIGIBLE Appearance and Odor:ODORLESS,TASTELESS WHITE SOLID OR POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BROMINE TRIFLUORIDE,2-FURANPERCARBOXYLIC ACID. Stability Condition to Avoid:HIGH HEAT. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,OXIDES OF BARIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.REGULATORY LEVEL FOR BARIUM IS 100MG/L.EPA WASTE NUMBER IS D005. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.