EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS -- 146 4700,CONC,KODAK DEKTOL DEVELOPER (SINGLE POWDER) -- 6750-00-945-6529
===================== Product Identification ===================== Product ID:146 4700,CONC,KODAK DEKTOL DEVELOPER (SINGLE POWDER) MSDS Date:06/18/1999 FSC:6750 NIIN:00-945-6529 Status Code:A === Responsible Party === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST City:ROCHESTER State:NY ZIP:14650-1115 Country:US Info Phone Num:716-722-5151/(800) 242-2424 Emergency Phone Num:716 722-5151 (800) 242-2424 CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 Contract Num:SP0500-96-D-9413-N858 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE MONOHYDRATE CAS:5968-11-6 Minumum % Wt:50. Maxumum % Wt:55. Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:30. Maxumum % Wt:35. Ingred Name:HYDROQUINONE CAS:123-31-9 RTECS #:MX3500000 = Wt:6. OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:4-(METHYLAMINO)PHENOL SULFATE CAS:55-55-0 RTECS #:SL8650000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:SODIUM HEXAMETAPHOSPHATE CAS:10124-56-8 RTECS #:OY3675000 Minumum % Wt:1. Maxumum % Wt:5. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD-50 (RAT): 0.5-5.0 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. AIRBORNE DUST IRRITAT ING. REPEATED EXPOSURE TO DUST MAY CAUSE EYE INJURY. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTRO INTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE):INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): HYDROQUINONE, GROUP 3 - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENIST S (ACGIH) (HYDROQUINONE): A3 - ANIMAL CARCINOGEN - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:CONTAINS: 4-(METHYLAMINO)PHENOL SULFATE. BASED ON ANIMAL DATA, MAY CAUSE ADVERSE EFFECTS ON THE FOLLOWING ORGANS/SYSTEMS: BLOOD, KIDNEY, SPLEEN. BASED ON ANIMAL DATA THIS MATERIAL CAN PRODUCE METHEMOG LOBIN WHICH, IN SUFFICIENT CONCENTRATION, CAUSES CYANOSIS, A BLUE-GRAY DISCOLORATION OF THE SKIN AND LIPS CAUSED BY A REDUCED ABILITY OF THE BLOOD TO CARRY OXYGEN. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: IMMEDIATELY FLUSH WITH WATER AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WI TH WATER AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN IRRITATION OR AN ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. D ESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR PO ISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. PERSONAL Other Precautions:PRECAUTIONARY MEASURES-AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) HAND CL EANER AND REGULAR CLEANING OF WORKING SURFACES, GLOVES, ETC. WILL MINIMIZE THE POSSIBILITY OF A SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: DUST. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR: ACID GAS. IF RESPIRATORS USED, ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES & PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE. Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND FACE SHIELD. Other Protective Equipment:WEAR A FULL-FACE RESPIRATOR, IF NEEDED. EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health VENTILATION: USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. ================== Physical/Chemical Properties ================== HCC:T6 Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Vapor Pres:@ 20?C (68?F):NEGLIGIBLE Spec Gravity:NOT AVAILABLE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE, ODORLESS SOLID. Percent Volatiles by Volume:NEGLIGIBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:STABLE. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SULFUR DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:HYDROQUINONE. IN F-344 RATS, CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN THE FORMATION OF BENIGN KIDNEY TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY. HYDROQUINONE-INDUCED NEPHROPATHY FOLLOWING ORAL ADMINISTRATION HAS BEEN NOTED IN THE MALE F-344 RAT, BUT NOT IN OTHER SPECIES OR RAT STRAINS TESTED. ALTHOUGH AN INCREASE IN MONONUCLEAR CELL LEUKEMIA IN F-344 FEMALE RATS HAS BEEN REPO RTED FOLLOWING CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE, THIS FINDING WAS NOT REPRODUCED IN A SUBSEQUENT STUDY. ===================== Ecological Information ===================== Ecological:SUMMARY: DATA FOR THE MAJOR COMPONENTS OF THIS MATERIAL HAVE BEEN USED TO ESTIMATE THE ENVIRONMENTAL IMPACT OF THIS MATERIAL. THIS MATERIAL FORMS AMODERATELY ALKALINE AQUEOUS SOLUTION, & THIS PROPERTY MAY CAUSE ADVERSE ENVIRONMENTAL EFFECTS. HOWEVER, THIS MATERIAL, ITSELF, HAS NOT BEEN TESTED FOR ENVIRONMENTAL EFFECTS. IT IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A MODERATE BIOCHEMICAL OXYGEN DEMAND & MAY CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS, A HIGH POTENTIAL TOAFFECT SOME AQUATIC ORGANISMS, A HIGH POTENTIAL TO AFFECT SECONDARY WASTETREATMENT MICROBIAL METABOLISM, A MODERATE POTENTIAL TO AFFECT THE GERMINATION.. AND/OR EAR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLD WIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: HYDROQUINONE Federal Regulatory Information:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE):- INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): HYDROQUINONE, GROUP 3. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENI STS (ACGIH) (HYDROQUINONE): A3 - ANIMAL CARCINOGEN. NATIONAL TOXICOLOGY PROGRAM (NTP): NONE. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE. State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.